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influence of curing conditions on the mechanical properties and leaching of inorganic polymers made of fayaliticslag

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 317-327 doi: 10.1007/s11705-017-1622-6

摘要： This study reports on the impact of the curing conditions on the mechanical properties and leaching of inorganic polymer (IP) mortars made from a water quenched fayalitic slag. Three similar IP mortars were produced by mixing together slag, aggregate and activating solution, and cured in three different environments for 28 d: a) at 20 °C and relative humidity (RH) ~ 50% (T20RH50), b) at 20 °C and RH≥90% (T20RH90) and c) at 60 °C and RH ~ 20% (T60RH20). Compressive strength (EN 196-1) varied between 19 MPa (T20RH50) and 31 MPa (T20RH90). This was found to be attributed to the cracks formed upon curing. Geochemical modelling and two leaching tests were performed, the EA NEN 7375 tank test, and the BS EN 12457-1 single batch test. Results show that Cu, Ni, Pb, Zn and As leaching occurred even at high pH, which varied between 10 and 11 in the tank test’s leachates and between 12 and 12.5 in the single batch’s leachates. Leaching values obtained were below the requirements for non-shaped materials of Flemish legislation for As, Cu and Ni in the single batch test.

关键词： inorganic polymer     geochemical leaching modelling     heavy metals     recycling     non-ferrous fayalitic slag     curing    

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赋含稀有及有色金属的长英质岩体岩石学与岩石地球化学对比分析

王子玺,凌锦兰,宋艳芳

《中国工程科学》 2015年 第17卷 第2期   页码 50-58

摘要：

长英质岩体常赋含Cu、Mo、W、Sn、Nb、Ta而形成稀有及有色金属矿床，大多数富矿岩体都属于小岩体（面积＜10 km2）。赋含铜钼矿的岩体中岩浆的SiO2、K2O、K2O/Na2O高有利于富集Mo；Al2O3、Fe2O3T、MgO、CaO含量高有利于富集Cu。赋含钨锡矿的岩体中岩浆的SiO2、K2O高有利于富集W；Al2O3、Fe2O3T、MgO、CaO含量高有利于富集Sn。赋含铌钽的岩体中岩浆中高Fe2O3T、低P2O5、富碱、高TiO2有利于Nb的富集。含Cu矿岩体基本都属I型花岗岩，而含Mo矿岩体属由I型到S型的过渡类型；赋含钨锡矿的岩体基本属于S型花岗岩；而赋含铌钽矿的长英质岩体成因类型复杂，I型、S型、A型花岗岩均有。

关键词： 长英质岩体；稀有金属；有色金属；岩石成因；小岩体    

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清洁高效的提取冶金——矿浆电解

邱定蕃

《中国工程科学》 1999年 第1卷 第1期   页码 67-72

摘要：

环境污染和能源短缺是重有色金属冶炼的两大障碍。在对重有色金属湿法冶金存在主要问题进行分析的基础上研究成功的矿浆电解新技术，是一种清洁、高效的提取冶金。它具有流程短、能耗低、金属分离好和环境污染少等特点。矿浆电解的显著特点是充分利用了电积过程的阳极反应来浸出矿石，工艺能耗大大降低；在电解槽中硫化物转化为元素硫，而不产生硫酸，有利于环境保护。文章描述了国内外矿浆电解技术的发展过程及我国建立的世界上第一个矿浆电解工业生产厂的概况，指出我国在该领域处于世界领先地位和矿浆电解技术具有很好的前景。

关键词： 重有色金属     湿法冶金     矿浆电解     提取冶金    

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中国铜铝铅锌矿产资源开发利用现状及安全供应战略研究

孙传尧,宋振国,朱阳戈,吴熙群

《中国工程科学》 2019年 第21卷 第1期   页码 133-139 doi: 10.15302/J-SSCAE-2019.01.019

摘要：

作为国民经济发展的重要基础原料，铜、铝、铅、锌是消费量最大的有色金属。近十多年来，中国铜、铝、铅、锌产量和消费量连续高居世界第一，但矿山资源产量远不能满足国内的消费需要，对外依存度居高不下。本文通过对中国铜、铝、铅、锌开发利用现状研究和未来需求预测，分析了国内外资源及二次资源对其消费需求的保障程度，据此制定铜、铝、铅、锌矿产资源安全供应战略，从国内供应、境外开发、国际市场三方面，在矿产品、再生金属以及精炼金属三个环节，定量构建未来20年有色金属安全保障目标，通过加大国内勘查开发力度、提高国内供应能力、坚持境内资源绿色可持续开发、加强二次资源回收、积极利用境外资源等多种途径，保障有色金属资源安全。

关键词： 矿产资源     有色金属     安全供应     铜、铝、铅、锌    

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高熵合金材料研究进展与展望

李天昕,王书道,卢一平,曹志强 ,王同敏,李廷举

《中国工程科学》 2023年 第25卷 第3期   页码 170-181 doi: 10.15302/J-SSCAE-2023.03.016

摘要：

随着世界科技水平的快速发展以及国民经济建设对高性能合金材料的迫切需求，传统单一主元合金逐渐不能满足人们与日俱增的使役需求。高熵合金因其独特的物理、化学以及力学性能，极大地拓展了金属材料成分设计范围，有望在国防、航空、航天、海洋、核能、医疗、新能源等重大工程领域发挥重要作用。本文结合各领域对先进高熵合金材料的具体需求，梳理了高熵合金材料的特征和内涵，分析了高熵合金材料发展的整体形势与前景，厘清了国内外高熵合金的发展现状。在此基础上，指出了我国高熵合金领域存在的差距和不足，我国高熵合金部分基础原材料依赖进口，严重威胁产业链安全；高熵合金产学研用体系尚未健全，工业化应用方面的研发投入有待提高。针对上述问题，研究建议，加强高熵合金材料研发的顶层设计，完善产业政策；加强企业和科研机构的对接和沟通；完善高熵合金材料标准、测试、表征、评价体系；推进人才队伍建设；降低材料成本，打造高附加值产品，促进我国先进高熵合金材料产业朝着体系化、绿色化、高端化、智能化方向发展。

关键词： 高熵合金；新材料；有色金属；关键战略材料；结构材料；功能材料    

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Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

《结构与土木工程前沿（英文）》 2022年 第16卷 第1期   页码 117-130 doi: 10.1007/s11709-021-0788-7

摘要： Proven research output on the behavior of structures made of waste copper slag concrete can improve its utilization in the construction industry and thereby help to develop a sustainable built environment. Although numerous studies on waste copper slag concrete can be found in the published literature, no research has focused on the structural application of this type of concrete. In particular, the variability in the strength properties of waste copper slag concrete, which is required for various structural applications, such as limit state design formulation, reliability-based structural analysis, etc., has so far not attracted the attention of researchers. This paper quantifies the uncertainty associated with the compressive-, flexural- and split tensile strength of hardened concrete with different dosages of waste copper slag as fine aggregate. Best-fit probability distribution models are proposed based on statistical analyses of strength data generated from laboratory experiments. In addition, the paper presents a reliability-based seismic risk assessment of a typical waste copper slag incorporated reinforced concrete framed building, considering the proposed distribution model. The results show that waste copper slag can be safely used for seismic resistant structures as it results in an identical probability of failure and dispersion in the drift demand when compared with a conventional concrete building made of natural sand.

关键词： waste copper slag     quantification of variability     goodness-of-fit test     seismic risk assessment     PSDM    

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Utilization of alkali-activated copper slag as binder in concrete

《结构与土木工程前沿（英文）》 2021年 第15卷 第3期   页码 773-780 doi: 10.1007/s11709-021-0722-z

摘要： This study was focused on developing concrete using alkali-activated copper slag (AACS) as a binder. The properties of alkali-activated copper slag concrete (AACSC) were compared with portland cement concrete (PCC). Different AACSC mixes were prepared with varying Na2O dosage (6% and 8% of the binder by weight) and curing methods. Hydration products in AACSC were retrieved using Fourier-transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD) techniques. The test results indicate that the workability of AACSC was lesser than that of PCC. The AACSC mix with 6% Na2O dosage has exhibited similar mechanical properties as that of PCC. The mechanical properties of AACSC were higher than PCC when 8% of Na2O dosage was used. Heat curing was effective to upgrade the strength properties of AACSC at an early age of curing, but at a later age mechanical properties of ambient cured and heat-cured AACSC were comparable. The hydration products of AACSC were not identified in XRD patterns, whereas, in FTIR spectra of AACSC some alkali-activated reaction products were reflected. The AACSC mixes were found to be more sustainable than PCC. It has been concluded that AACSC can be produced similarly to that of PCC and ambient curing is sufficient.

关键词： binder     concrete     mechanical properties     mineralogy     workability    

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Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 460-469 doi: 10.1007/s11705-022-2224-5

摘要： Nitric oxide being a major gas pollutant has attracted much attention and various technologies have been developed to reduce NO emission to preserve the environment. Advanced persulfate oxidation technology is a workable and effective choice for wet flue gas denitrification due to its high efficiency and green advantages. However, NO absorption rate is limited and affected by mass transfer limitation of NO and aqueous persulfate in traditional reactors. In this study, a rotating packed bed (RPB) was employed as a gas–liquid absorption device to elevate the NO removal efficiency (ηNO) by aqueous persulfate ((NH4)2S2O8) activated by ferrous ethylenediaminetetraacetate (Fe2+-EDTA). The experimental results regarding the NO absorption were obtained by investigating the effect of various operating parameters on the removal efficiency of NO in RPB. Increasing the concentration of (NH4)2S2O8 and liquid–gas ratio could promoted the oxidation and absorption of NO while the ηNO decreased with the increase of the gas flow and NO concentration. In addition, improving the high gravity factor increased the ηNO and the total volumetric mass transfer coefficient (KGα) which raise the ηNO up to more than 75% under the investigated system. These observations proved that the RPB can enhance the gas–liquid mass transfer process in NO absorption. The correlation formula between KGα and the influencing factors was determined by regression calculation, which is used to guide the industrial scale-up application of the system in NO removal. The presence of O2 also had a negative effect on the NO removal process and through electron spin resonance spectrometer detection and product analysis, it was revealed that Fe2+-EDTA activated (NH4)2S2O8 to produce •SO4–, •OH and •O2–, played a leading role in the oxidation of NO, to produce NO3– as the final product. The obtained results demonstrated a good applicable potential of RPB/PS/Fe2+-EDTA in the removal of NO from flue gases.

关键词： rotating packed bed     Fe2+-EDTA     sulfate radical     hydroxyl radical     NO removal efficiency    

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Effect of fly ash and slag on concrete: Properties and emission analyses

Vivian W. Y. TAM, Khoa N. LE, Ana Catarina Jorge EVANGELISTA, Anthony BUTERA, Cuong N. N. TRAN, Ashraf TEARA

《工程管理前沿（英文）》 2019年 第6卷 第3期   页码 395-405 doi: 10.1007/s42524-019-0019-2

摘要： Recycled concrete is a material with the potential to create a sustainable construction industry. However, recycled concrete presents heterogeneous properties, thereby reducing its applications for some structural purposes and enhancing its application in pavements. This paper provides an insight into a solution in the deformation control for recycled concrete by adding supplementary cementitious materials fly ash and blast furnace slag. Results of this study indicated that the 50% fly ash replacement of Portland cement increased the rupture modulus of the recycled concrete. Conversely, a mixture with over 50% cement replacement by either fly ash or slag or a combination of both exhibited detrimental effect on the compressive strength, rupture modulus, and drying shrinkage. The combined analysis of environmental impacts and mechanical properties of recycled concrete demonstrated the possibility of optimizing the selection of recycled concrete because the best scenario in this study was obtained with the concrete mixture M8 (50% of fly ash+ 100% recycled coarse aggregate).

关键词： recycled aggregate     recycled concrete     fly ash and slag    

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Enhanced carbon tetrachloride degradation by hydroxylamine in ferrous ion activated calcium peroxide

Wenchao Jiang, Ping Tang, Zhen Liu, Huan He, Qian Sui, Shuguang Lyu

《环境科学与工程前沿（英文）》 2020年 第14卷 第2期 doi: 10.1007/s11783-019-1197-1

摘要： Complete CT degradation was achieved by employing HA to CP/Fe(II)/FA process. Quantitative detection of Fe(II) regeneration and HO• production was investigated. Benzoic acid outcompeted FA for the reaction with HO•. CO2•− was the dominant reductive radical for CT removal. Effects of solution matrix on CT removal were conducted. Hydroxyl radicals (HO•) show low reactivity with perchlorinated hydrocarbons, such as carbon tetrachloride (CT), in conventional Fenton reactions, therefore, the generation of reductive radicals has attracted increasing attention. This study investigated the enhancement of CT degradation by the synergistic effects of hydroxylamine (HA) and formic acid (FA) (initial [CT] = 0.13 mmol/L) in a Fe(II) activated calcium peroxide (CP) Fenton process. CT degradation increased from 56.6% to 99.9% with the addition of 0.78 mmol/L HA to the CP/Fe(II)/FA/CT process in a molar ratio of 12/6/12/1. The results also showed that the presence of HA enhanced the regeneration of Fe(II) from Fe(III), and the production of HO• increased one-fold when employing benzoic acid as the HO• probe. Additionally, FA slightly improves the production of HO•. A study of the mechanism confirmed that the carbon dioxide radical (CO2•−), a strong reductant generated by the reaction between FA and HO•, was the dominant radical responsible for CT degradation. Almost complete CT dechlorination was achieved in the process. The presence of humic acid and chloride ion slightly decreased CT removal, while high doses of bicarbonate and high pH inhibited CT degradation. This study helps us to better understand the synergistic roles of FA and HA for HO• and CO2•− generation and the removal of perchlorinated hydrocarbons in modified Fenton systems.

关键词： Calcium peroxide     Hydroxylamine     Modified Fenton     Reactive oxygen species     Perchlorinated hydrocarbon    

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Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength

Shivang D. JAYSWAL; Mahesh MUNGULE

《结构与土木工程前沿（英文）》 2022年 第16卷 第5期   页码 576-588 doi: 10.1007/s11709-022-0826-0

摘要： Previous studies on concrete have identified silica fume (SF) as the most effective supplementary material, whereas fly ash (FA) and slag have been identified as economical materials with long term strength potential. Development of blended cement mortar referred to as blended mortar (BM) requires similar assessment. The present study explores the application of Alccofine (AL) as supplementary material and compares its performance with conventional materials namely SF, FA and ground granulated blast furnace slag (GGBS). The mortar specimens with binder to fine-aggregates (b/f ) ratio of 1:2 are prepared at water to binder (w/b) ratios of 0.4 and 0.35. The strength values and stress-strain curve for control and BM specimens are obtained at 7, 28, 56, and 90 d curing periods. The assessment based on strength activity index, k-value method and strength estimation model confirms that AL, despite lower pozzolanic activity, contributes to strength gain, due to reduced dilution effect. Assessment of stress-strain curves suggests that the effect of w/b ratio is more dominant on the elastic modulus of BM specimens than on control specimens. The observations from the study identify enhanced strength gain, improved elastic modulus and higher energy absorption as key contributions of AL making it a potential supplementary material.

关键词： Alccofine     high strength mortar     efficiency factor     dilution effect    

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我国黑色金属资源发展形势研判

“黑色金属矿产资源强国战略研究”专题组

《中国工程科学》 2019年 第21卷 第1期   页码 97-103 doi: 10.15302/J-SSCAE-2019.01.014

摘要：

作为供给侧结构性改革的先行者，中国钢铁行业积极化解过剩产能，彻底取缔“地条钢”，2016—2017年化解钢铁产能超过1.2×108t，清除“地条钢”等违法产能1.4×108t。当前，全球钢铁工业处于产能过剩周期，中国钢铁消费由持续增长向“峰值平台区”转变，单位GDP粗钢消费强度回落，单位投资粗钢消费强度下降，预计到2025年国内粗钢消费需求量为6×108~6.5×108t，产量为6.5×108~7.0×108t，到2030年，国内粗钢消费需求量为5.3×108~6.0×108t，产量为5.9×108~6.5×108 t。与此同时，我国废钢资源供给量将快速增加，未 来充足的废钢资源将是我国钢铁工业强有力的支撑，铁素资源构成也将发生重大变化，国际铁矿石资源的需求量将逐步下降，同时对于推动生态文明建设和绿色发展具有重要作用。

关键词： 钢铁     废钢     铁矿石     峰值平台区    

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network model on tensile behavior of hybrid steel-PVA fiber reinforced concrete containing fly ash and slag

Fangyu LIU, Wenqi DING, Yafei QIAO, Linbing WANG

《结构与土木工程前沿（英文）》 2020年 第14卷 第6期   页码 1299-1315 doi: 10.1007/s11709-020-0712-6

摘要： The tensile behavior of hybrid fiber reinforced concrete (HFRC) is important to the design of HFRC and HFRC structure. This study used an artificial neural network (ANN) model to describe the tensile behavior of HFRC. This ANN model can describe well the tensile stress-strain curve of HFRC with the consideration of 23 features of HFRC. In the model, three methods to process output features (no-processed, mid-processed, and processed) are discussed and the mid-processed method is recommended to achieve a better reproduction of the experimental data. This means the strain should be normalized while the stress doesn’t need normalization. To prepare the database of the model, both many direct tensile test results and the relevant literature data are collected. Moreover, a traditional equation-based model is also established and compared with the ANN model. The results show that the ANN model has a better prediction than the equation-based model in terms of the tensile stress-strain curve, tensile strength, and strain corresponding to tensile strength of HFRC. Finally, the sensitivity analysis of the ANN model is also performed to analyze the contribution of each input feature to the tensile strength and strain corresponding to tensile strength. The mechanical properties of plain concrete make the main contribution to the tensile strength and strain corresponding to tensile strength, while steel fibers tend to make more contributions to these two items than PVA fibers.

关键词： artificial neural network     hybrid fiber reinforced concrete     tensile behavior     sensitivity analysis     stress-strain curve    

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含钒钢渣中钒再资源化的基础研究

董元篪,武杏荣,余　亮,李辽沙

《中国工程科学》 2007年 第9卷 第1期   页码 63-68

摘要：

采用熔融－冷却方法并在渣中分别添加SiO2和Al2O3进行改性，讨论了含钒钢渣中钒的富集以及钒 富集相的结晶与生长。研究表明，在添加SiO2的含钒钢渣中，钒由分布在2CaO·SiO2(C2S)和2CaO·Fe2O3(C2F)。两个相中转变为集中分布在Ca3[(V,P,Si)]O4]2固溶体相中，其中 V2O的质量分数达到24.38％，但是生 成的钒富集相晶体尺寸较小；在添加Al2O3的钢渣中，钒同样也富集在 Ca3[(V,P,Si)]O4]2 固溶体相中，其中 V2O5 的质量分数达到14.90％。晶化试验表明 ， 钒富集相核化存在非均匀核化与均匀核化 ， 温度分别在1350℃ 和1325 ℃ ； 在1300 ℃ 保温条件下，钒富集相的晶体由 5 min 的 6.24 μm 生长到 580 min 的 25.19 μm，单位面积上的晶体数随之下降 。

关键词： 含钒钢渣     富集     钒富集相     晶体生长     固溶体    

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Mercury removal from flue gas using nitrate as an electron acceptor in a membrane biofilm reactor

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1454-y

摘要：

Membrane bioreactor achieved mercury removal using nitrate as an electron acceptor.

关键词： Mercury removal     Oxygen     Ferrous sulfide     Transformation of mercury     Microbial community    

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标题 作者 时间 类型 操作

influence of curing conditions on the mechanical properties and leaching of inorganic polymers made of fayaliticslag

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

期刊论文

赋含稀有及有色金属的长英质岩体岩石学与岩石地球化学对比分析

王子玺,凌锦兰,宋艳芳

期刊论文

清洁高效的提取冶金——矿浆电解

邱定蕃

期刊论文

中国铜铝铅锌矿产资源开发利用现状及安全供应战略研究

孙传尧,宋振国,朱阳戈,吴熙群

期刊论文

高熵合金材料研究进展与展望

李天昕,王书道,卢一平,曹志强 ,王同敏,李廷举

期刊论文

Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete

期刊论文

Utilization of alkali-activated copper slag as binder in concrete

期刊论文

Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate

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Effect of fly ash and slag on concrete: Properties and emission analyses

Vivian W. Y. TAM, Khoa N. LE, Ana Catarina Jorge EVANGELISTA, Anthony BUTERA, Cuong N. N. TRAN, Ashraf TEARA

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Enhanced carbon tetrachloride degradation by hydroxylamine in ferrous ion activated calcium peroxide

Wenchao Jiang, Ping Tang, Zhen Liu, Huan He, Qian Sui, Shuguang Lyu

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Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength

Shivang D. JAYSWAL; Mahesh MUNGULE

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我国黑色金属资源发展形势研判

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network model on tensile behavior of hybrid steel-PVA fiber reinforced concrete containing fly ash and slag

Fangyu LIU, Wenqi DING, Yafei QIAO, Linbing WANG

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含钒钢渣中钒再资源化的基础研究

董元篪,武杏荣,余　亮,李辽沙

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Mercury removal from flue gas using nitrate as an electron acceptor in a membrane biofilm reactor

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